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51.
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国外引种松树松脂化学组成的特征 总被引:8,自引:4,他引:8
W.B.Critchfield和E.L.Little,Jr.将油松组松树分成6个亚组。本文采用GC、GC-MS方法对分属4个亚组的16种国外引种松树松脂化学组成的特征进行研究,发现每一个亚组的松脂各有其特点。马尾松、黄山松等国内松树树种与黑松、琉球松、同属一个亚组,其松脂的化学特征比较相似;而与湿地松、火炬松等另一亚组松脂则有较大区别,说明亚组的划分有利于松树的化学分类。不同地理变种的加勒比松松脂 相似文献
54.
Anupun Terdwongworakul Vittaya Punsuwan Warunee Thanapase Satoru Tsuchikawa 《Journal of Wood Science》2005,51(2):167-171
Near-infrared (NIR) spectroscopy has been demonstrated as a means for rapid nondestructive determination of the chemical composition and final pulp yield of Eucalyptus camaldulensis in Thailand tree plantations. Multiple linear regression (MLR) analysis and partial least squares (PLS) analysis were introduced to develop statistical models in terms of calibration equations for total pulp yield, screened pulp yield, and contents of -cellulose, pentosans, and lignin in wood. In MLR analysis, a reasonably good calibration equation was found only for pentosans (standard error of prediction (SEP): 0.98%). The PLS analysis improved the accuracy of prediction for every criterion variable, especially for pentosans (SEP: 0.91%) and lignin (SEP: 0.52%). Also, in the case of screened pulp yield, we were able to use such a statistical result as an indicator of the characteristics of the pulp and paper. Thus, NIR spectroscopy could be satisfactorily used as an effective assessment technique for Eucalyptus camaldulensis plantation trees. 相似文献
55.
Heat treatments change the chemical and physical properties of wood and dimensional stability and hygroscopicity are affected
as a result of modifications of wood cell components. This study evaluated the water absorption of wood specimens treated
with boron compounds followed by heat treatment. Sugi (Cryptomeria japonica D. Don) sapwood specimens treated with either boric acid (BA) or disodium octoborate tetrahydrate (DOT) solutions were heat-modified
at either 180° or 220°C for 2 or 4 h. Carbohydrate composition and water absorption of the specimens were then measured and
compared with those of untreated and unheated specimens. Wood carbohydrates were significantly degraded in the specimens after
heat treatment. The heat treatment evidently decreased the water absorption and the heat-modified specimens absorbed less
water than unheated specimens. The higher the treatment temperature and the longer the treatment time, the lower the amount
of absorbed water. The boron-treated and heat-modified specimens, however, showed increased water absorption due to the hygroscopic
properties of BA and DOT. 相似文献
56.
57.
材性改良研究:Ⅰ.X射线木材密度测定 总被引:6,自引:2,他引:6
利用X射线衍射(D-max3B型)改装成直接扫描式X射线木材密度计,可快速、高效测定木材密度组成,即木材平均密度,平均早材密度,平均晚材密度,最大木材密度,最小木材密度,木材密度梯度和木材密度的变异幅度,为材性改良提供了新手段,本文用X射线木材密度计测定17个树种木材密度。 相似文献
58.
Sugi (Cryptomeria japonica D. Don) wood was treated with supercritical water (374°C, 22.1MPa), and fractionated into the water-soluble portion, the methanol-soluble portion, and the methanol-insoluble residue. The methanol-soluble portion mainly consisted of the lignin-derived products. To characterize the compounds in the methanol-soluble portion, gel permeation chromatographic (GPC) and gas chromatographic-mass spectrometric (GC-MS) analyses were performed. The GPC analysis indicated that the methanol-soluble portion contained lignin-derived monomeric and dimeric products. GC-MS analysis detected 31 products which were expected to be monomeric compounds, and 18 of these were identified to be guaiacol, methylguaiacol, ethylguaiacol, vinylguaiacol, eugenol, propylguaiacol, vanillin, cis-isoeugenol, homovanillin, trans-isoeugenol, acetoguaiacone, propioguaiacone, guaiacylacetone, 2-methoxy-4-(1-hydroxypropyl)phenol, homovanillic acid, 2-methoxy-4-(prop-1-en-3-one)phenol, coniferyl aldehyde, and ferulic acid. In addition, 22 dimeric products were detected, and 4 of these were believed to be compounds with biphenyl type (5-5), diphenylethane type (-1), stilbene type (-1), and phenylcoumaran type (-5) structures. These results clearly indicated that the methanol-soluble portion included various monomeric and dimeric compounds produced as a result of the cleavage of ether linkages and propyl chains of lignin. 相似文献
59.
In order to investigate the effects of chemical components and matrix structure on the destabilization of quenched wood, we
examined the physical and mechanical properties of steam-treated wood, hemicellulose-extracted wood, and delignified wood,
which were treated at different levels. For steam-treated and hemicellulose-extracted wood,the relative relaxation modulus
of the quenched sample was lower than that of the respective control sample. For delignified wood, the relative relaxation
modulus fell with weight loss and reached a minimum value at a certain weight loss, and subsequently increased significantly.
The hygroscopicity of all treated samples changed slightly by steaming, whereas increased with removing the component. More-over,
the average volumetric swelling per 1% MC at 100% relative humidity (RH) was less than at 75% RH and 93% RH for component-removed
wood. It was clear that a void structure existed. As a result, the destabilization evaluated by the fluidity (1 - E
t/E
0) of steam-treated wood was influenced by the amount of adsorbed water. For component-removed wood, destabilization increased
temporarily at lower weight loss because of nonuniform cohesive structure. At high weight loss, destabilization will decreased
because capillary-condensed water gathered in the voids and obstructed the motion of adsorbed water. However, the destabilization
of all treated wood changed less than that of chemically modified wood. 相似文献
60.